Characterisation And Dielectric Property Analysis of A-site Doped LaTiO3-δ Perovskites Synthesised by Ball Milling Method

The present work highlights a series of perovskites La0.8A0.2TiO3-δ, (where A= Ba, Ca, Sr), which includes a high dielectric constant, a low dielectric loss over a wide temperature, in a frequency range of 30 MHZ. Undoped and A-site doped LaTiO3-δ (with Ba 2+ , Sr 2+ and Ca 2+ ) perovskites were synthesised by solid state reaction method (ball milling). The perovskite phase formation of the milled precursor powders under thermal treatments was investigated by thermogravimetry/differential scanning calorimetry (TG/DSC). Structural analysis of the phase pure sintered pellets revealed an orthorhombic crystal structure for all perovskites. Surface morphology of the sintered pellets exposed the presence of nanosized grains. The oxidation states of La 3+ and Ti 3+ ions have been confirmed using X-ray Photoelectron Spectroscopy (XPS). The dielectric spectral analysis reveals that dielectric properties of the perovskites depend on temperature and frequency. Among the dopants Sr is found to be