Hg(II) Adsorption By Alginate-guar Gum Templated Titania Spheres: Kinetic And Isotherm Studies

In present communication we report on the kinetic and isotherm studies on Hg(II) removal using our recently reported material, the millimeter sized hollow titania spheres (TSP). The mesoporous spheres with high surface area (11.75 m 2 /g) and bimodal pore size distribution were fabricated by a facile sol-gel approach using alginate-guar gum hybrid beads as the structure directing agent. In order to investigate the utility of TSP for Hg(II) adsorption, the batch adsorption experiments were conducted at various pH values (2–7), initial Hg(II) concentrations (50–300 mg/L), and TSP doses (20-100 mg) at 150 rpm, and 30 °C temperature. The spheres exhibited good capacity to adsorb Hg(II) in wide pH range (pH 3 to pH 7). It was possible to remove >95 % Hg(II) from 100 mg/L synthetic Hg(II) solution at pH 5, and 50 mg TSP dose in 10 h. The adsorption equilibrium data were better fitted to Langmuir model at low temperatures while Freundlich model become favored as the temperature was increased